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The Short Answer:
Sunlight reaches Earth's atmosphere and is scattered in all directions by all the gases and particles in the air. Blue light is scattered more than the other colors because it travels as shorter, smaller waves. This is why we see a blue sky most of the time.
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Riemann's green is a green pigment ZnO.CoO, which is obtained by heating a mixture of zinc oxide and cobalt nitrate or by the reaction of cobalt nitrate with either or zinc sulphate.
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