Sigma bond is stronger than Pi bond because of the following reasons:

1. The extent of overlapping in Sigma bond is greater than in Pi bond.
2. The electron density in intermolecular axis is more in Sigma bond than in Pi bond.
3. There is free rotation of atom about Sigma bond but not about Pi bond.

The two vectors (say A and B) of different magnitudes cannot be combined to give zero resultant since minimum value of combination is ІA-BІ which is not zero if AB.

The three vectors A, B and C of different magnitudes can be zero such that they form a closed triangle, then,

      A+B+C=0

or, C=-(A+B)

Hence, the sum of three vectors may be zero if vector sum of any two vectors is equal and opposite to the third vector.

Note: The vectors can give this result only if...

Yes, a vector which has zero magnitude is also a vector in case of two vectors travelling in opposite directions with equal magnitudes. At this case, the resultant vector has zero magnitude but it is still a vector. We call it a null vector.