Yes, a physical quantity can have magnitude and direction but still be a scalar if it doesn't obey the vector addition. An example is Electric Current which has magnitude and a fixed direction, but it does not follow vector laws of addition.

1. sol:

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Sigma bond is stronger than Pi bond because of the following reasons:

1. The extent of overlapping in Sigma bond is greater than in Pi bond.
2. The electron density in intermolecular axis is more in Sigma bond than in Pi bond.
3. There is free rotation of atom about Sigma bond but not about Pi bond.