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Sigma bond is formed due to the overlapping of orbitals along their intermolecular axis. This leads to the effective overlapping and high electron density along intermolecular axis.

On the other hand, a pi bond is formed due to the sideways overlapping of orbitals. This side-ways overlap is partial and results in low electron density in intermolecular axis.

This is why, a sigma bond is stronger than pi bond.

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