Compounds with hydrogen bonding tend to have higher melting and boiling points because the hydrogen bonding leads to stronger intermolecular forces. Intermolecular forces are the attractive forces between molecules, and they affect the physical properties of a substance, including melting and boiling points.

Hydrogen bonding is a particularly strong type of intermolecular force that occurs when a hydrogen atom is bonded to a highly electronegative atom such as nitrogen, oxygen, or fluorine....

Here, the given equation of parabola is y²= 8x.

The equation of tangent to the parabola y²=8x is,

y= mx + 2/m

This tangent passes through the point (-2, 3)

So, 3 = -2m + 2/m

or, 3m + 2m² = 2

or, 2m²+3m - 2= 0

or, 2m² + (4 - 1)m -2 = 0

or, 2m² + 4m - m - 2 = 0

or, 2m(m + 2) - 1(m+2) = 0

or, (m + 2) (2m - 1) = 0

Either, Or,

m = -2 m = 1/2

Required angle is,

Sigma bond is stronger than Pi bond because of the following reasons:

1. The extent of overlapping in Sigma bond is greater than in Pi bond.
2. The electron density in intermolecular axis is more in Sigma bond than in Pi bond.
3. There is free rotation of atom about Sigma bond but not about Pi bond.