Sunlight reaches Earth's atmosphere and is scattered in all directions by all the gases and particles in the air. Blue light is scattered more than the other colors because it travels as shorter, smaller waves. This is why we see a blue sky most of the time.

Log_2aa=x    then, a=(2a)^x  ......(1)

Log_3a2a=y    then,2a=(3a)^y ......(2)

Log_4a 3a=z  then, 3a=(4a)^z ......(3)

So, 

a=(2a)^x  [from (1)]

Or, a=(3a)^xy    [from(2)]

Or, a=(4a)^xyz     [from(3)]

Multiplying both sides by 4a,

4a.a=4a.(4a)^xyz  

Or,(2a)² =(4a)^{xyz + 1} 

Or,(3a)^2y =(4a)^xyz+1 

Or,(4a)^2yz =(4a)^xyz+1 

Or, 2yz = xyz+1 .proved.

Sigma bond is stronger than Pi bond because of the following reasons:

1. The extent of overlapping in Sigma bond is greater than in Pi bond.
2. The electron density in intermolecular axis is more in Sigma bond than in Pi bond.
3. There is free rotation of atom about Sigma bond but not about Pi bond.

The difference between Gram atomic  mass and Gram atomic molecular are given below: