a)When silver nitrate comes in contact with skin, it is reduced to white color metallic silver.In most cases, a black stain appears due to formation of finely divided silver which has black color.
The black color is due to the decomposition of the Ag+ ion into Ag, silver. Silver nitrate will slowly decompose with the silver ion reverting to elemental silver. The microscopic particles of silver are so small that they absorb light instead of reflecting it, and so appear black, instead of silver....
zinc will react with sulphuric acid forming zinc sulphate dissolved in solution and releasing hydrogen gas.
Zn + conc. 2 H2SO4 ZnSO4 + SO2 + 2 H2O
Yes, a physical quantity can have magnitude and direction but still be a scalar if it doesn't obey the vector addition. An example is Electric Current which has magnitude and a fixed direction, but it does not follow vector laws of addition.

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