Sigma bond is stronger than Pi bond because of the following reasons:

1. The extent of overlapping in Sigma bond is greater than in Pi bond.
2. The electron density in intermolecular axis is more in Sigma bond than in Pi bond.
3. There is free rotation of atom about Sigma bond but not about Pi bond.

In benzene molecule, carbon and carbon bond can't have polarity because there is not any electronegativity difference and the carbon hydrogen is also not much polar because the electronegativity difference is almost zero and also the small pull due to small difference in Electronegativity is balanced due to even pull from all directions.

In chlorobenzene the electronegativity difference between carbon and chlorine is very high so, it is polar.

(to compare polarity first check electronegativity...

SinceECu2+/CuECu2+/Cuhas a greater positive value thanEH+/HEH+/H, the reaction that is feasible at the cathode is

Cu2+(aq)+2eCu(s)

The two vectors (say A and B) of different magnitudes cannot be combined to give zero resultant since minimum value of combination is ІA-BІ which is not zero if AB.

The three vectors A, B and C of different magnitudes can be zero such that they form a closed triangle, then,

      A+B+C=0

or, C=-(A+B)

Hence, the sum of three vectors may be zero if vector sum of any two vectors is equal and opposite to the third vector.

Note: The vectors can give this result only if...