21 Chemistry -- Non-Metals: Allotropes of Oxygen

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Introduction

⁕ Introduction to Oxygen

↪ Greek, Oxys - Sour, genas - produce: Acid Producer






















Symbol O
Atomic number 8
Atomic mass 16 amu
Valency 2
Electronic configuration

1s2 2s2 2p4

⁕ Occurrence

↪ English chemist Joseph Priestly detected oxygen in 1774 as a nonmetallic element.
↪ Oxygen is the most abundant element and it is about 47% by mass on the earth crust in the form of oxides and oxysalts.
↪ It occurs 23% by weight in free molecular form in air and about 86% by weight in combined form on oceans.
↪ Natural oxygen is a mixture of three isotopes:
16O(99.76%), 17O(0.04%) and 18O(0.2%).
↪ Oxygen is the most essential for life and it supports respiration.

⁕ Position of Oxygen in Periodic table

↪ Oxygen is a nonmetallic element having atomic number 8 and mass number 16.
↪ Its electronic configuration is: 1s2 2s2 2p4.
↪ The elements sulphur, selenium, tellurium and polonium also have general valence shell electronic configuration ns2 np4 and all of them belongs to group VIA.
↪ All these elements are collectively called chalcogens (ore forming) because metal occur in nature as the ores of oxides, sulphides, selenides and tellurides.
↪ Oxygen is the representative element of this family.

⁕ Electronic configuration and some properties of group VIA elements are given below:





































Element Atomic Number Electronic Configuration I.P. (ev) E.N.
O 8 [He] 2s2 2p4
13.6 3.5
S 16 [Ne] 3s2 3p4
10.35 2.5
Se 34 [Ar] 3d10 4s2 4p4
9.75 2.4
Te 52 [Kr] 4d10 5s2 5p4
9.01 2.1

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