PRINCIPLE OF VOLUMETRIC ANALYSIS
1) According to the law of chemical equivalance, "Substances reacts completely with each other in the equal no of their gram equivalents.|"
i.e No. of of gram equiv. of one substance = no. of gram equiv. of another substance.
2) At equivalence point, normality equation holds true.
i.e N1V1=N2V2
3) Concentration of solution is inversely proportional to dilution.
eg. 100 cc of 1N solution = (100*10) cc of N/10 solution.
x ml of y N solution = (x*y) ml of 1N solution.
4) Equal strength of solution neutralize in equal volume.
eg. 10 ml of 1 N NaoH = 10 mo of 1N HCl
1000 ml of 1N HCl = 1 gm equiv. of NaoH
5) For the mixture of acid or bases:
N1V1+N2V2+................+ Nn*Vn = Nm*Vm
where Nm= normality of resulting solution.
and Vm= total volume of mixture.
6) For the mixture of acid and Bases:-
Na*Va - Nb*Vb = Nm*Vm
if Nm is +ve then resulting solution is acidic.
if Nm is -ve then resulting solution is basic. and if Nm=0 then the solution is neutral.